Identification of charge separated states in thymine single strands.

نویسندگان

  • Bert M Pilles
  • Dominik B Bucher
  • Lizhe Liu
  • Peter Gilch
  • Wolfgang Zinth
  • Wolfgang J Schreier
چکیده

UV excitation of the DNA single strand (dT)18 leads to electronically excited states that are potential gateways to DNA photolesions. Using time-resolved infrared spectroscopy we characterized a species with a lifetime of ∼100 ps and identified it as a charge separated excited state between two thymine bases.

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عنوان ژورنال:
  • Chemical communications

دوره 50 98  شماره 

صفحات  -

تاریخ انتشار 2014